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By W G Frankenburg; V I Komarewsky; Eric K Rideal

ADVANCES IN CATALYSIS quantity 3.

content material: entrance disguise; Advances in Catalysis and similar matters, quantity III; Copyright web page; Contents; participants to quantity III; Editors' Preface; bankruptcy 1. Balandin's Contribution to Heterogeneous Catalysis; I. advent; II. The Multiplet conception; III. dialogue of the idea; IV. Steric issues in Catalysis; References; bankruptcy 2. Magnetism and the constitution of Catalytically lively Solids; I. advent; II. normal ideas; III. Experimental equipment; IV. The Susceptibility Isotherm; V. Supported Chromium Oxide; VI. Supported Oxides of Manganese; VII. Supported Nickel Oxide VIII. Supported Iron OxideIX. Supported Copper Oxide; X. comparable structures; XI. Self-Supported platforms; XII. Ferromagnetism; XIII. identity of Ferromagnetic levels; XIV. response approaches; XV. resolution approaches; XVI. precis; References; bankruptcy three. Catalytic Oxidation of Acetylene in Air for Oxygen Manufacture; I. advent; II. situation of Air and Acetylene; III. Acetylene elimination; IV. Catalyst Compositions; V. Regeneration; VI. Mechanism of the Oxidation Reactions; VII. Mechanism of the Oxidation by means of Silver Nitrate; References; bankruptcy four. The Poisoning of metal Catalysts I. Catalysts prone to PoisoningII. critical different types of Catalyst Poisons; III. the shape of Catalyst Poisoning Curves; IV. additional components Influencing Toxicity; V. important Poisoning; References; bankruptcy five. Catalytic Cracking of natural Hydrocarbons; I. advent; II. Catalytic Cracking Reactions; III. Catalytic Cracking of Paraffins; IV. Catalytic Cracking of Olefins; V. Catalytic Cracking of Naphthenes; VI. Catalytic Cracking of fragrant Hydrocarbons; VII. constitution of Cracking Catalysts; References; bankruptcy 6. Chemical features and constitution of Cracking Catalysts I. IntroductionII. size of the "Acidity" of Cracking Catalysts; III. identity of the Acid facilities because the Catalytically energetic websites; IV. constitution of the Acid; V. Mechanism of Hydrocarbon Reactions on a Cracking Catalyst; References; bankruptcy 7. response charges and Selectivity in Catalyst Pores; I. advent; III . The actual photo of the Pore constitution; III. Mechanism of delivery in Catalyst Pores; IV. actual elements making a choice on response charges on Porous Catalysts . (Definition of fee Constants, the basic Differential Equation and the legislation of Conservation of Mass V. response charges in unmarried PoresVI. response premiums on sensible Catalyst Pellets; VII. response charges on Poisoned Catalysts (Apparent Selective Poisoning); VIII. impact of Pore constitution on Catalyst Selectivity; Appendix; thesaurus of Symbols; References; bankruptcy eight. Nickel Sulfide Catalysts; I. advent; II. The Nickel-Sulfur Equilibrium; III. actual Adsorption of Gases on Ni2S2 Catalysts; IV. Chemisorption of Gases on Ni2S2; V. helps for Stabilizing Nickel Sulfide; VI. instruction of Nickel Sulfide Catalysts; VII. worthy lifestyles and Regeneration
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96 Solution Processes. . . . . . . . . . . . . . . 1. Introduction. . . . . 2. Catalyst Preparation. . . . . . . . . . . . . . . . . 98 3. Magnetic Data . . . . . . . . . . . . . . . . . . . . . . . . . 100 4. Diffusion in Powdered Metals.. 101 5. Interpretation of Morris-Selwoo . . . . . . . . . . . 102 . . . . . . . 104 Summary.. . . . . . . . . . . . . . References . . . . . . . . .

93 2. Cobalt Carbide . . . . . . . . . . . . . . . . . . . . . . . . . 96 Solution Processes. . . . . . . . . . . . . . . 1. Introduction. . . . . 2. Catalyst Preparation. . . . . . . . . . . . . . . . . 98 3. Magnetic Data . . . . . . . . . . . . . . . . . . . . . . . . . 100 4. Diffusion in Powdered Metals.. 101 5. Interpretation of Morris-Selwoo .

The samples, which are often in powdered form, may be measured in glass tubes, a small correction being made for the diamagnetism of the glass. For a tube of 8 mm. external diameter, 12 cm. long, and a field of 8ooo gauss, the forces exerted on samples, such as are discussed later FIG. 1. Principle of the GouY method for memuring MAGNETISM AND CATALYTICALLY ACTIVE SOLIDS 31 in this article, range from a few tenths of a milligram to several hundred milligrams. ' 2. Temperature Control In all magnetic measurements on paramagnetic substances it is virtually indispensable to know the temperature coefficient of susceptibility.

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